Advances in Elastomers I: Blends and Interpenetrating by P. Deepalekshmi, P. M. Visakh, Aji. P. Mathew, Arup K.

By P. Deepalekshmi, P. M. Visakh, Aji. P. Mathew, Arup K. Chandra (auth.), P. M. Visakh, Sabu Thomas, Arup K. Chandra, Aji. P. Mathew (eds.)

This is the 1st quantity of a two-volume paintings which summarizes in an edited layout and in a pretty complete demeanour some of the fresh technical examine accomplishments within the quarter of Elastomers. “Advances in Elastomers” discusses some of the makes an attempt suggested on fixing those difficulties from the perspective of the chemistry and the constitution of elastomers, highlighting the drawbacks and benefits of every process. It summarize the significance of elastomers and their multiphase platforms in human existence and undefined, and covers the entire themes relating to fresh advances in elastomers, their blends, IPNs, composites and nanocomposites.

This first quantity makes a speciality of advances at the blends and interpenetrating networks (IPNs) of elastomers.

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Polyhedral oligomeric silsequioxanes (POSS) are single molecule nanofillers that have received much recent attention, for example they have been used as part of the polyol components in polyurethane elastomers. Thermogravimetry showed that POSS-polyurethane hybrids have increased thermal stability due to an influence of POSS on ther degradation mechanism [39]. Thermoplastic elasomers based on poly(ethyleneco-vinyl acetate) have been used to form nanocomposies with organo-modified layered double hydroxides (LDH) where the LDH exfoliated upon dispersion.

Shanks and I. Kong developed for a great number of biomedical applications such as controlled drug delivery systems, hydrogels, tissue engineering, and other uses [23, 24] . 3 Thermoplastic Polyether Ester Elastomers The polyether ester elastomers or copolyesters (COPEs) consist of sequence of hard and soft segments. The high melting blocks (hard segments) are formed by the crystalline polyester segments which are capable of crystallization and the rubbery soft segments are formed by the amorphous polyether segments with a relatively low glass transition temperature.

Some that have been used are diene rubbers and polyolefins, butyl and halobutyl rubbers and polyolefin Elastomer Hard Polymer Fig. 17 Development of morphology in a thermoplastic vulcanizates from a co-continuous phase to dispersed phase 38 R. A. Shanks and I. Kong resins, polyacrylate rubber and polyolefins [30] and butadiene-acrylonitrile rubber and polyvinyl chloride [31]. ). There are three decisive characteristics in order to obtain TPVs with good balance of properties: the wetting surface tensions (Dc) of the elastomeric and thermoplastic components, the fraction of crystallinity (WC) of the thermoplastic and the critical entanglement spacing (NC) of the elastomer macromolecules [32].

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